How to stop Explorer from opening in the Libraries

If you want to change the default location for Windows Explorer to open (Libraries), here’s how:

1. Right click the Explorer icon on the taskbar.
2. Hold down Shift and right click the Windows Explorer icon in the Jump List.
3. Select Properties.
4. On the Shortcut tab, change the Target field to open to the location of your choice.
5. Click OK.

To change it to open to My Documents, change the Target field to:
%SystemRoot%\explorer.exe /N,::{450D8FBA-AD25-11D0-98A8-0800361B1103}

To open to any other folder, change to:
%SystemRoot%\explorer.exe folder path

-Summey